Cucumber Peels for Ecofriendly Food Packaging

Are you throwing away the cucumber peels after preparing your salad? You may soon have them back in your kitchen as the eco-friendly packaging material for food items.

IIT Kharagpur researchers have developed cellulose nanocrystals from cucumber peels with high cellulose content, compared to other peel wastes, which can be used to create food packaging materials.

While single-use plastic is consciously being avoided by consumers, they still remain largely in circulation as food packaging items. Natural biopolymers are unable to make way in this industry as they lack strength, elongation, barrier property, optical property, and in some cases even biological safety. The cellulose nanomaterial developed by researchers, Prof. Jayeeta Mitra and N. Sai Prasanna at IIT Kharagpur’s Dept. of Agricultural and Food Engineering from raw cucumber waste, has addressed this challenge.

What are cellulose nanocrystals?

Food packaging materials require nano-filler reinforced bio-composites which can be derived from the cellulose widely available from the outer skin of fruits and vegetables. These cellulose fibres can be used to produce cellulose nanocrystals (CNCs), bio-based nanomaterials with defined nano-scale structural dimensions. They are produced through controlled acid hydrolysis which removes amorphous regions, and produces more crystalline regions.

The product from raw to final form: Top – Cucumber Peels, Bottom Left – Raw Fibre, Right – Dried cellulose nanocrystals

Cucumber-based CNCs Developed by IIT Kharagpur Researchers

In India, cucumber finds wide use in salads, pickles, cooked vegetables or consumed raw and also in the beverage industry leading to a large volume of peel biowaste which is rich in cellulose content.

“Cucumbers generate about 12% residual wastes obtained after processing either the peels or whole slices as waste. We have used the celluloses, hemicellulose, pectin extracted from this processed material for deriving new bio-materials which are useful as nano-fillers in bio-composites,” said Dr.  Jayeeta Mitra, Assistant Professor at the Dept. of Agricultural and Food Engineering.

Talking about the findings, she further added, “Our study shows that cellulose nanocrystals derived from cucumber peels possess modifiable properties due to the presence of abundant hydroxyl groups, which resulted in better biodegradability and biocompatibility. These nanocellulose materials emerged as strong, renewable and economic material of the near future, due to unique properties like a high surface area to volume ratio, light in weight, and excellent mechanical properties. Thereby, such nanocrystals, when reinforced as nano-fillers in bio-composites films, can produce effective food packaging materials with low oxygen permeabilities.”

Schematic sketch on cellulose nanocrystals through acid hydrolysis

The present study revealed that cucumber peels possessed greater cellulose content (18.22%) than other peel waste. It also provided better insights into their crystalline, thermal and colloidal properties of cucumber cellulose.

Research scholar N. Sai Prasanna said, “The crystallinity percentage as high as 74.1 % along with thermal stability of more than 200 °C negative zeta potential values (< -30 mV), and acid hydrolysis yield of 65.55%, make the material a strong nano-filler reinforcement as bio-nano composite. This offers the much needed mechanical, barrier, optical, rheological properties, nontoxicity, etc. required for food packaging materials which has the strong market potential to replace plastic.”

Market Potential – Application of CNCs and Environmental Sustainability

This non-toxic, biodegradable and biocompatible product has no adverse effects on health and the environment hence could have a huge market potential by rendering management of organic waste with high cellulose content profitable.

“Apart from the food packaging and beverage industries the researchers are optimistic about its scope in various fields like thermo-reversible and tenable hydrogels making, paper making, coating additives, food packaging materials, bio-composites, optically transparent films, as stabilizers in oil-water emulsion. Also, CNCs find good potential applications in biopharmaceutical applications such as drug delivery and fabricating temporary implants like sutures, stents etc.,” added Sai Prasanna.

The researchers further made a note for packaging industry players in our country for substantial investments to improve packaging material properties for better sustainability, disposal and decomposition issues. All these demands for biodegradable packaging will propel the nanocellulose market in the coming timeframe contributing towards a sustainable and plastic-free world, opined Prof. Mitra.

“The incremental usage of petroleum-based plastics in food packaging, spanning a few decades, has raised many challenges as these plastics are the indomitable sources of environmental pollution since nearly 60% of it is converted to landfill, and rest is recycled only once. More research and product development focused on various biopolymers from either macromolecules or from the microbial polymers would be able to make the sector acceptable to packing material producers with wider awareness, alternative products at economic prices,” she remarked.

Cite this paper: Prasanna, N. S., & Mitra, J. (2020). Isolation and characterization of cellulose nanocrystals from Cucumis sativus peels. Carbohydrate Polymers247, 116706. https://doi.org/10.1016/j.carbpol.2020.116706

Contacts:

For Research:

Dr. Jayeeta Mitra, Assistant Professor  

Agricultural & Food Engineering Department

Email: jayeeta.mitra@agfe.iitkgp.ac.in

For Media:

Shreyoshi Ghosh, EO (M&C)

Office of Director, IIT Kharagpur

E: shreyoshi@adm.iitkgp.ac.in

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About Dept. of Agricultural and Food Engineering

IIT Kharagpur has the sole distinction of having a department in the area of Agricultural & Food Engineering, which comprises six disciplines such as Farm Machinery and Power, Land and Water Resources Engineering, Agricultural Biotechnology, Food Process Engineering, Agricultural Systems Management and Aquacultural Engineering, respectively. The major domain of research and development includes Precision agriculture, biofuel and bioenergy, modern food processing, plasticulture and micro-irrigation, Climate Change, hydrological modeling, groundwater management, water management, agricultural biotechnology, pollution abatement, extrusion technology, intelligent and high-pressure packaging, soil mapping and image analysis for plant phenotyping. Sponsored research projects and development activities deal with Integrated Rainwater Management, Soil Tillage, Utilisation of Fly ash, Ergonomic Database for Agricultural Equipment, Integrating Remote Sensing Data with Distributed Hydrological Models, Model Pilot Plant and koji room facilities for the production of industrial enzymes etc. More info . . .

IIT Kharagpur Researchers Develop Industry-grade Silica from Rice Biomass

Rice husk is one of the most widely available agricultural wastes. The process of disposal of rice husks looks more crucial as burning the material each year during the winters has been creating a severe environmental challenge. While the husk is often used to meet energy requirements for rice milling, this process produces an enormous amount of ash (approx. 20%) which is a hazardous material to the environment. Researchers at IIT Kharagpur have devised an economic and eco-friendly way to dispose of this biowaste.

A team of researchers from IIT Kharagpur’s Dept. of Agricultural and Food Engineering have developed a chemical treatment which can separate the silica content in the husk ash residue which is about 90 – 95% and neutralize the remaining biomass for disposal in water bodies. 

“The silica extracted on purification has the potential of commercial grade silica which can further be used for production of metallurgical and solar grade silicon, confirmed the researchers,” said lead researcher Prof. A K Datta.

 

Four different alkalis, namely, KOH, K2CO3, NaOH, and Na2CO3, and two different solvents, namely, water and alcohol (ethanol) were selected to accomplish the extraction process. The physical and chemical characterizations of the extracted silica were evaluated using a field-emission scanning electron microscope attached with energy dispersive X-ray spectrometer, X-ray diffractometer, Fourier-transform infrared spectrometer, and atomic absorption spectrophotometer.

To make the process eco-friendly and pollution-free, the rice husk ash was initially dispersed into the water and then Na2CO3 was added to it. As a result, carbonic acid was produced instead of CO2, which is harmless for the environment. 

“The results of the study suggested that the morphological, microstructural and compositional characteristics of the extracted silica nanoparticles (SiO2-NPs) are at par with the market available silica” explained Prof. Datta. 

The researchers have conducted a cost analysis of the treatment of silica samples to compare the costs with market grade silica. The result of the study suggested that the silica nanoparticle obtained from rice husk ash  can be a suitable low cost precursor for Magnesium silicide.

Research Paper Citation: 

Nayak, P., Datta, A. Synthesis of SiO2-Nanoparticles from Rice Husk Ash and its Comparison with Commercial Amorphous Silica through Material Characterization. Silicon (2020). https://doi.org/10.1007/s12633-020-00509-y


Contact:

Project: Prof. A K Datta, Dept. of Agricultural and Food Engineering, Email: akd@agfe.iitkgp.ac.in

Media: Shreyoshi Ghosh, Executive Officer (Media & Communication), E: shreyoshi@adm.iitkgp.ac.in


About Dept. of Agricultural and Food Engineering, IIT Kharagpur

The Agricultural and Food Engineering Department is unique of its kind in the IIT system focusing on agricultural research and food and nutritional security. The department comprises six disciplines such as Farm Machinery and Power, Land and Water Resources Engineering, Agricultural Biotechnology, Food Process Engineering, Agricultural Systems Management and Aquacultural Engineering, respectively. The major domain of research and development includes Precision agriculture, biofuel and bioenergy, modern food processing, plasticulture and micro-irrigation, Climate Change, hydrological modeling, groundwater management, water management, agricultural biotechnology, pollution abatement, extrusion technology, intelligent and high pressure packaging, soil mapping and image analysis for plant phenotyping. Research projects include Integrated Rainwater Management, Soil Tillage, Utilisation of Fly ash, Ergonomic Database for Agricultural Equipment, Integrating Remote Sensing Data with Distributed Hydrological Models, Model Pilot Plant and koji room facilities for production of industrial enzymes etc. The department has high-throughput equipment, NABL accredited Analytical Food Testing laboratory, Advanced Laboratories in varied domains. The department has filed several patent applications and transferred many technologies to the industries and various stake-holders based on its innovative research. 

Contact Head of the Dept.

Prof. Rintu Banerjee

Phone: +91-3222-282244; Email : head@agfe.iitkgp.ac.in

It’s Illumination Time

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Walking down the halls of residence at the IIT Kharagpur campus during the Diwali festival one would come across giant bamboo structures and busy students tying earthen lamps (diyaas) to them in patterns. There is no rush for firecrackers among the 12000 strong student population of IIT Kharagpur but a wait for the Diwali eve when any visitor would be awed by the lighted canvas telling stories from Indian history and mythology, Indian or global political issues, socio-economic issues etc.

When the country is debating the ban on firecrackers and whether to extend the same to other festivities and celebrations; when people are still hoping to get lucky with the green crackers which have been out of stock in the market; when the world is still debating about climate change with groups trying to find perspectives in the voices raised by climate change evangelists; the students in their late teens and 20s have quietly established a tradition of going green every Diwali for the past four decades.

 “Our campus is stretched across 2100 acres but the halls of residence are located in a particular area. Think what would we do to our homes at Kgp if thousands of firecrackers are burnt for an entire evening! Instead, in typical IIT KGP style our seniors in the early 1980s turned this challenge into an opportunity and pledged to shun air pollution and replace it with creativity, teamwork, innovation and leading to creating art forms which was named Illumination,” said a proud Akshat Jain, 3rd year UG student of Agricultural and Food Engineering department, who also heads the Public Relations Chair of Technology Students Gymkhana, the student nerve centre of IIT Kharagpur.

In the true spirit of Diwali, Illumination disseminates a wave of excitement and enthusiasm throughout the campus. It marks the triumph of endless night-outs, mammoth hours of planning and exemplary teamwork uniting the whole campus community and making a yearly statement of how nature can be saved following a long-standing tradition. To begin with, the basic raw materials comprising of steel wires, bamboo, and diyas, students transform them into magnificent structures with unique themes varying with Halls of residence which shine against the dark making every KGPian proud and spirited. The diyas are hung to designing of gigantic canvasses made of bamboo structures or Chatais about 20 ft high with an average area of 1500 sq.ft. On the eve of Diwali as the visitors start coming in one hall after another start lighting up these diyas creating a mesmerising view to which only professional artistes may be able to compete.

“This culture is followed by 23 halls of residence where artist’s canvases are created and these artistes are none other than students of IIT Kharagpur. Such a non-polluting way of celebration benefiting the local community both environmentally and economically in this scale would be difficult to find elsewhere in the world to the best of my knowledge. Illumination I would say, is the indigenous festival of IIT Kharagpur,” beamed Akshat.

Talking about this green Diwali tradition, Officiating Director of IIT Kharagpur Prof. Sriman Kumar Bhattacharyya said, “Illumination is done with a grandeur without causing any harm to the environment. It is a green process because the students do not burn any material which could be considered as highly pollutant. This could also be observed the day following Diwali when the air at the IIT Kharagpur campus as fresh as the other days unlike the scenario in most urban areas.”

This led to a direct, positive impact on the campus environment by preventing unwanted noise and air pollution while at the same time saving large on electricity expenditure on the day of Diwali by going traditional. And then there is the novelty of supporting the livelihood of local shopkeepers selling the materials required for this celebration. 

Together with Illumination is another indispensable part of Diwali at IIT Kharagpur – “Rangoli”. The IIT KGP Rangoli is very different from what is traditionally thought of as Rangoli per se. These are huge murals made on the floor with colors mixed with sand. The sand is sifted at least a hundred times to get a fineness that is silvery smooth when running through the fingers. The colours are sourced locally or sometimes, from South India, for some colours that are rare. Students work on deciding the theme and design and ultimately executing the work. The themes are multifarious – scenes from myths, folklore or contemporary accounts of violence or victory, addressing social issues and achievements of Indians.

This unique festival of IIT Kharagpur has more takers than the campus residents and students. Just like pandal hopping, thousands of visitors from outside the campus do hostel hopping on the eve of Diwali before the diyas run out of oil and the wind takes charge. The festival is also highly popular with the international students who enthusiastically take part in the preparation in their respective halls of residence.

Prof. Anandroop Bhattacharya, Associate Dean of International relations of the institute who was alumnus of 1997 batch said that “illumination  event is something every KGPian is proud of. Nowhere is  Diwali celebrated in the world as it is done at  IIT KGP. Through decades we have been able to show that there is a clean and green way of celebrating Diwali.”

To share the art form with more connoisseurs from the global community, this year the Office of International Relations launched a holistic short-term certification program Dyuti focussing on Indian science, technology, heritage and culture with a workshop on Illumination and Rangoli. International students of various nationalities who are already studying in India joined the week-long programme are to join the day-long workshop at the halls of residence where they will take part in the making of the grand designs and take back home an experience which can transform festivities across the globe to cleaner celebrations without missing the joy of it.

Risk Perceptions Challenging Green Lighting

India Today

Are perceived risks making Indians shy away from eco-friendly LED lighting? – Researchers at IIT Kharagpur’s Vinod Gupta School of Management find concurrence in a study pointing out at consumer psychology and perceived high-cost factor which might be slowing down the growth of the Indian LED lighting market.

The UJALA scheme by Govt. of India had been aiming to make a transition to LED for all lighting needs by 2019. This could have helped the nation save over ₹ 40,000 crore a year. But looking at the sales figures in 2018, the market share of incandescent bulbs, CFLs, and traditional tube lights still exceeded LED lamps and TLEDs by 116 million pieces. Domestic consumers, who account for about 24% of the total electricity demand in the country, are skeptical and perceive a high level of risk when it comes to purchasing and usage of green products.

What is holding them back? Prof. Sangeeta Sahney and research scholar Sujit Kumar Ray from Vinod Gupta School of Management conducted a PAN India study which suggests financial, psychological, physical, and performance risks perceived by consumers as among the potential reasons behind such conservative buying behaviour, the financial and psychological risks being the key among them. (Access Full Paper)

An LED bulb costs almost 4 times of traditional tube light and close to 15 times of incandescent bulbs. Does the extra cost incurred in purchasing an LED light bulb match the benefits of energy efficiency as claimed? This is a question which a consumer often ponders on while making the buying decision at a retail shop and finally settles with traditional lighting systems, opines Prof. Sahney, based on the study. But LED bulbs are proven power savers with energy efficiency as 9 watts for light output requiring 15 watts and 28 watts in case of CFL and traditional tube lights. This leads to a reduction in electricity usage for an estimated period of 6 hours per day for 5 years to ₹ 493/- for LED bulbs as against the cost of ₹821/- and ₹1533/- for CFL and traditional lighting (assuming average unit cost ₹ 5) thus reducing total cost by 52% and the energy cost by 68%.

Another critical factor observed in the study was the Indian consumers’ psychological barrier in this transition to energy efficient lighting system. Since the technology is still new in the minds of the Indian consumers, they may not be fully aware of the effectiveness of the products available in the market.

“Consumers’ faith on green products get compromised when it comes to their purchase behavior due to their perception that green products have lower value, may not deliver performance as per expectation, and in no case are consumers likely to compromise on value, performance, and price,” says researcher Sujit Kumar Ray in his paper “Indian consumers’ risk perception in buying green products: the case of LED light bulbs” published in the Asia Pacific Journal of Marketing and Logistics recently.

Sujit and Prof. Sahney recommend nationwide campaign to increase consumer awareness regarding benefits of LED bulbs such as warranty available for LED bulbs or if rebates on electricity bills and promotional discounts can be offered to first time users.

Author of the paper may be contacted at sujitkumar@iitkgp.ac.in