Studying Plastic Pollution in the Ganga with National Geographic

Ganga, the life source of Northern and Eastern India is a prominent area of study by researchers from diverse disciplines, a key among them is the environment. In 2019, the National Geographic Society organized the expedition “Sea to Source: Ganges” to scientifically document plastic waste in the Ganges watershed and support holistic and inclusive solutions. A proud partner in this women scientists-led expedition was IIT Kharagpur along with the Isabela Foundation, University of Dhaka, the Wildlife Institute of India, and Wild Team Bangladesh.

Researchers and students from an environment-focused group at the Dept. of Civil Engineering, IIT Kharagpur participated in this transboundary expedition. The group was involved in estimating the mismanaged plastic quantities from municipal solid waste all along the river in India and come up with potential solutions and improvements in waste management systems to avoid the leakages of plastic waste from land to the river.

Talking about their role in the study-based expedition, Prof. Brajesh Dubey who heads this group at IIT Kharagpur said, “We carried out the waste characterization from the city/town dumpsite waste samples, as well as the samples collected along the river from Rishikesh to Howrah. It helped in estimating the extent of mismanaged plastics in the waste, the type of plastics present in the waste and the estimation of the fraction of mismanaged waste plastics getting into the river Ganga. A model is also being developed using the field data to have a realistic estimation of the plastic pollution transport from land to river and eventually to the ocean.”

The IIT research group also performed a photographic survey of waste management practices and issues for each city/town. Further, they held and discussions with city officials on waste management plans, identification of infrastructure gaps for the city/town and suggestions for improvement in the implementation of the solutions for better plastic waste management.  The solutions proposed include the proper waste collection in segregation mode, capacity building in terms of infrastructure development as well as skill improvement of manpower involved in waste management practices at ULB levels.  The research group is in touch with several ULBs for the improvement of their waste management infrastructure. 

While the expedition was carried out from May to December 2019, the study was carried out till February 2021. The report has been recently made public by the National Geographic Society on their blog. Read More

Photo by Sara Hylton.

Times of India

Cucumber Peels for Ecofriendly Food Packaging

Are you throwing away the cucumber peels after preparing your salad? You may soon have them back in your kitchen as the eco-friendly packaging material for food items.

IIT Kharagpur researchers have developed cellulose nanocrystals from cucumber peels with high cellulose content, compared to other peel wastes, which can be used to create food packaging materials.

While single-use plastic is consciously being avoided by consumers, they still remain largely in circulation as food packaging items. Natural biopolymers are unable to make way in this industry as they lack strength, elongation, barrier property, optical property, and in some cases even biological safety. The cellulose nanomaterial developed by researchers, Prof. Jayeeta Mitra and N. Sai Prasanna at IIT Kharagpur’s Dept. of Agricultural and Food Engineering from raw cucumber waste, has addressed this challenge.

What are cellulose nanocrystals?

Food packaging materials require nano-filler reinforced bio-composites which can be derived from the cellulose widely available from the outer skin of fruits and vegetables. These cellulose fibres can be used to produce cellulose nanocrystals (CNCs), bio-based nanomaterials with defined nano-scale structural dimensions. They are produced through controlled acid hydrolysis which removes amorphous regions, and produces more crystalline regions.

The product from raw to final form: Top – Cucumber Peels, Bottom Left – Raw Fibre, Right – Dried cellulose nanocrystals

Cucumber-based CNCs Developed by IIT Kharagpur Researchers

In India, cucumber finds wide use in salads, pickles, cooked vegetables or consumed raw and also in the beverage industry leading to a large volume of peel biowaste which is rich in cellulose content.

“Cucumbers generate about 12% residual wastes obtained after processing either the peels or whole slices as waste. We have used the celluloses, hemicellulose, pectin extracted from this processed material for deriving new bio-materials which are useful as nano-fillers in bio-composites,” said Dr.  Jayeeta Mitra, Assistant Professor at the Dept. of Agricultural and Food Engineering.

Talking about the findings, she further added, “Our study shows that cellulose nanocrystals derived from cucumber peels possess modifiable properties due to the presence of abundant hydroxyl groups, which resulted in better biodegradability and biocompatibility. These nanocellulose materials emerged as strong, renewable and economic material of the near future, due to unique properties like a high surface area to volume ratio, light in weight, and excellent mechanical properties. Thereby, such nanocrystals, when reinforced as nano-fillers in bio-composites films, can produce effective food packaging materials with low oxygen permeabilities.”

Schematic sketch on cellulose nanocrystals through acid hydrolysis

The present study revealed that cucumber peels possessed greater cellulose content (18.22%) than other peel waste. It also provided better insights into their crystalline, thermal and colloidal properties of cucumber cellulose.

Research scholar N. Sai Prasanna said, “The crystallinity percentage as high as 74.1 % along with thermal stability of more than 200 °C negative zeta potential values (< -30 mV), and acid hydrolysis yield of 65.55%, make the material a strong nano-filler reinforcement as bio-nano composite. This offers the much needed mechanical, barrier, optical, rheological properties, nontoxicity, etc. required for food packaging materials which has the strong market potential to replace plastic.”

Market Potential – Application of CNCs and Environmental Sustainability

This non-toxic, biodegradable and biocompatible product has no adverse effects on health and the environment hence could have a huge market potential by rendering management of organic waste with high cellulose content profitable.

“Apart from the food packaging and beverage industries the researchers are optimistic about its scope in various fields like thermo-reversible and tenable hydrogels making, paper making, coating additives, food packaging materials, bio-composites, optically transparent films, as stabilizers in oil-water emulsion. Also, CNCs find good potential applications in biopharmaceutical applications such as drug delivery and fabricating temporary implants like sutures, stents etc.,” added Sai Prasanna.

The researchers further made a note for packaging industry players in our country for substantial investments to improve packaging material properties for better sustainability, disposal and decomposition issues. All these demands for biodegradable packaging will propel the nanocellulose market in the coming timeframe contributing towards a sustainable and plastic-free world, opined Prof. Mitra.

“The incremental usage of petroleum-based plastics in food packaging, spanning a few decades, has raised many challenges as these plastics are the indomitable sources of environmental pollution since nearly 60% of it is converted to landfill, and rest is recycled only once. More research and product development focused on various biopolymers from either macromolecules or from the microbial polymers would be able to make the sector acceptable to packing material producers with wider awareness, alternative products at economic prices,” she remarked.

Cite this paper: Prasanna, N. S., & Mitra, J. (2020). Isolation and characterization of cellulose nanocrystals from Cucumis sativus peels. Carbohydrate Polymers247, 116706. https://doi.org/10.1016/j.carbpol.2020.116706

Contacts:

For Research:

Dr. Jayeeta Mitra, Assistant Professor  

Agricultural & Food Engineering Department

Email: jayeeta.mitra@agfe.iitkgp.ac.in

For Media:

Shreyoshi Ghosh, EO (M&C)

Office of Director, IIT Kharagpur

E: shreyoshi@adm.iitkgp.ac.in

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About Dept. of Agricultural and Food Engineering

IIT Kharagpur has the sole distinction of having a department in the area of Agricultural & Food Engineering, which comprises six disciplines such as Farm Machinery and Power, Land and Water Resources Engineering, Agricultural Biotechnology, Food Process Engineering, Agricultural Systems Management and Aquacultural Engineering, respectively. The major domain of research and development includes Precision agriculture, biofuel and bioenergy, modern food processing, plasticulture and micro-irrigation, Climate Change, hydrological modeling, groundwater management, water management, agricultural biotechnology, pollution abatement, extrusion technology, intelligent and high-pressure packaging, soil mapping and image analysis for plant phenotyping. Sponsored research projects and development activities deal with Integrated Rainwater Management, Soil Tillage, Utilisation of Fly ash, Ergonomic Database for Agricultural Equipment, Integrating Remote Sensing Data with Distributed Hydrological Models, Model Pilot Plant and koji room facilities for the production of industrial enzymes etc. More info . . .

How safe is your tea in a paper cup?

IIT Kharagpur Research Gives Evidence of Microplastic Pollution in the Hot Liquid Consumed from Disposable Paper Cups

With the current crusade against single-use plastic, disposable paper cups are on the rise especially for consuming water and hot beverages. But even these cups are not without peril. Recent research by IIT Kharagpur has confirmed contamination of the hot liquid served in paper cups due to the degradation of microplastics and other hazardous components from the lining material of the cup. 

Paper cups are usually lined by a thin layer of hydrophobic film which is made of mostly plastic (polyethylene) and sometimes co-polymers to hold the liquid in the paper cup. Within 15 minutes this microplastic layer degrades as a reaction to hot water, says the first of its kind study conducted in India by Dr. Sudha Goel, Associate Professor at the Dept. of Civil Engineering and research scholars Ved Prakash Ranjan and Anuja Joseph studying Environmental Engineering and Management.

The paper ‘Microplastics and other harmful substances released from disposable paper cups into hot water’ has been published in the Journal of Hazardous Materials recently. [https://doi.org/10.1016/j.jhazmat.2020.124118]. 

“According to our study, 25,000 micron-sized (10 µm to 1000 µm) microplastic particles are released into 100 mL of hot liquid (85 – 90 oC) residing in the paper cups for 15 mins. Thus, an average person drinking 3 regular cups of tea or coffee daily, in a paper cup, would be ingesting 75,000 tiny microplastic particles which are invisible to the human eyes,” says Prof. Sudha Goel. 

The researchers followed two different procedures – in the first process, hot ultrapure (MilliQ) water (85–90 ◦C; pH~6.9) was poured into the disposable paper cups,  and it was allowed to sit for 15 mins. The homogeneously mixed water was then analyzed for the presence of microplastics as well as additional ions that may have leached into the liquid from the paper cups. In the second process, paper cups were initially dipped in lukewarm (30–40 °C) MilliQ water (pH~6.9). Thereafter the hydrophobic film was carefully separated from the paper layer and exposed to hot MilliQ water (85–90 °C; pH~6.9) for 15 mins. and Changes in the physical, chemical, and mechanical properties of the plastic films were examined before and after exposure to hot water.

Explaining the exposure of 15 minutes, Prof. Goel linked its basis to a survey wherein the respondents confirmed consuming their beverage within 15 mins of obtaining it.

“Besides the result of the survey, it was also observed that within this time, the beverage attained the ambient temperature,” she said. 

The samples of paper cups were collected from popular stores across Kharagpur, West Bengal. “Our study indicates most plastic layers lining the paper cups were of HDPE (High-density polyethylene) grade, whereas only very few paper cups were lined with a copolymer of cellulose. However, the release of microplastics into the hot water was consistent in all samples irrespective of their grades,” remarked researcher Ved Prakash Ranjan.  

Apart from the presence of ions, the study also revealed that the plastic layer was laden with toxic heavy metals like Palladium, Chromium, and Cadmium.

“Our hypothesis on the degradation of the plastic layer after exposure to hot water was confirmed through images obtained from the atomic force and scanning electron microscopy. Also, another study on the mechanical properties of the plastic film proved its deformation upon exposure to heat,” explained researcher Anuja Joseph.

What could be the effect of long-term exposure to such microplastics? 

Prof. Sudha Goel expressed concern over the bioaccumulation of microplastics in human and animal bodies.

“These microplastics can further act as carriers for contaminants like ions, toxic heavy metals and organic compounds which are similarly hydrophobic in nature thus allowing them to conveniently cross over to the animal kingdom. When ingested, the health implications could be serious,” she opined.

While the research to study the health impact of microplastics is relatively limited, researchers are assertive about adverse effects from both the environmental and health point of view. Such materials have been repeatedly linked with child growth and organ development, reproduction issues, disruption of hormones, obesity etc. At a spring conference at the Rutgers Center for Urban Environmental Sustainability, a research group presented the possibility of passing microplastics from the mother’s body to even the fetus.

“These contaminants can bioaccumulate in organisms leading to health issues like the disruption of the endocrine system, reproductive defects, cancer, neurological disorders and other effects. There could be further health challenges such as the impact on the sense organs, immune dysfunction or even cancer. That remains for domain experts to confirm while we can foresee the environmental mayhem these particles are going to cause if gone unchecked,” stated Prof. Goel.

Several states in India have been mulling over restricting the use of paper cups but feasible alternatives are not yet on deck. Referring to the situation, Director, Prof. Virendra K Tewari called for careful consideration before the promotion of replacements for bio-hazardous products and environmental pollutants. He said,

“We have been quick to replace plastics cups and glasses with disposable paper cups. While the need was crucial we have to find eco-friendly products. India has traditionally been a country promoting sustainable lifestyle and may be it is time that we look into our roots for corrective measures.”

He wondered if earthen products can meet the consumer demand for disposable plastic and paper cups.

“Atmanirbhar Bharat has to be in our thinking before we adopt it in our lifestyle and the country’s economy and everything we do should have a reflection of that thought process and thereby in our consumption behaviour,” he added.


Cite this paper: Ranjan VP, Joseph A and S Goel [2020] Microplastics and other harmful substances released from disposable paper cups into hot liquids, Jour. of Hazardous Materials, 404 (124118): 1-12. https://doi.org/10.1016/j.jhazmat.2020.124118


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Contacts:

For Research: Dr. Sudha Goel, Associate Professor (Environmental Engineering & Management), Civil Engineering Department, sudhagoel@civil.iitkgp.ac.in

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IIT KGP Study Proposes Pandemic Waste Management Policy

IIT Kharagpur Study Proposes Solid Waste Management Policy to Counter Environmental Crisis during Pandemic

Covid-19 is impacting our daily lives in an unprecedented way, with one of the major impacts being on waste management programs across the world. While reduced economic activities due to COVID-19 have certainly made air and water cleaner as per many reports, change in the dynamics of plastic, food, and biomedical waste generation has however stirred the woes of solid waste management.

A recent study by IIT Kharagpur researchers has led to the formulation of a set of environmental recommendations for solid waste management under the pandemic situation. The researchers have explored the challenges faced by the solid waste management sector, typically cases in biomedical waste, plastic waste, and food waste management, during the pandemic and the underlying opportunities to fill existing loopholes in the system. [Download Paper]

The study led by Prof. Brajesh Kr. Dubey and his research group at IIT Kharagpur’s Dept. of Civil Engineering, has laid emphasis on the avenues of circular economy, sustainable technologies and development of green business models by analyzing the economic prospects in the post-pandemic world. 

“It should be well understood that the mess created by the COVID-19 crisis should not be solved at the expense of solving the longer-term issue of the climate crisis. The post-COVID-19 world would need a systems-level approach on a global scale to address the issue of solid waste management and protect our environment through economic stimulus with low carbon footprint,” said Dubey.

The study recommends the adoption of new technologies in solid waste management by means of socially viable designs scoring high on environmental and economic feasibility. Incentive policy could be introduced for adopting homogenous plastics, eco-friendly bioplastics, biodegradable materials with higher recyclability. This would enable the standardization of plastic products and packaging leading to economic recycling models. AI-powered sustainable technologies can be deployed to manage efficient sorting and recycling of waste. This shall be further supported by means of the ‘refuse, reduce, reuse and recycle’ mantra of the circular economy. 

“A typical example could be food waste management. Local production and consumption of food along with recycling and reuse leads to the reduction of food waste generation and recycling of food waste. Such models need to be introduced in overall solid waste management as well along with spreading awareness about the concept,” remarked researcher Hari Bhakta Sharma. 

Another area the study has focused on is the involvement of human resources in waste management. The researchers advocate for the provision of critical status to sanitation workers due to the risk involved in their work during a pandemic situation. This would involve supporting the educational and healthcare needs of their family members as well. Workers handling biomedical wastes also need to be trained adequately of international standards. Awareness needs to be created by means of universally accepted color-coded segregation of biomedical waste for proper classification of infectious waste, preventing excessive waste generation.

The researchers believe increasing public visibility through media and other platforms could indirectly bring behavioral and attitudinal changes in society. However, they also prioritized the need for inclusion of waste management in the disaster management protocol including response measures and operational guidelines. The study has been published in the international journal of ‘Resources, Conservation & Recycling’


Cite Paper: Sharma et al., 2020, H.B. Sharma, K. Vanapalli, V.R.S. Cheela, V.P. Ranjan, A.K. Jaglan, B. Dubey, Sudha Goel, J. Bhattacharya,

Challenges, opportunities, and innovations for effective solid waste management during and post COVID-9 pandemic

Resources, Conservation & Recycling, 2020 (2020), 10.1016/j.resconrec.2020.105052

Download Paper: https://doi.org/10.1016/j.resconrec.2020.105052


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Say No to Single-Use Plastic

Students at IIT KGP are working towards preventing single-use plastic usage

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About 30 students at IIT KGP have taken up the task of reducing single-use plastic usage in the campus. The students are in the process of forming a students’ society which among other environmental issues will extensively work towards creating social awareness in collecting and disposing of plastic waste including e-waste.

The students have led by example not using single-use plastic for over 4 months and inspiring other students in the campus to follow the feat. The group has also performed street plays in the campus market as part of the awareness campaign. Over 500 students have shown their interest in joining this society and take up the cause. The newly formed society named “Vision Prabaho”, would be undertaking projects to come up with innovative ways of organic, inorganic and electronic waste disposal.

“Segregation of waste is one issue and another is disposing of off the waste, reusing it. We hope these brilliant young minds would be able to come up with some innovations for urban Indians who are creating massive plastic waste which is causing problem for both urban and rural ecosystems,” said Barnali Chakrabarti, an environmental evangelist and the first lady of the campus.

The Prime Minister of India has been making extensive efforts to ‘Beat Plastic Pollution’– including an ambitious pledge to eliminate all single-use plastic in the country by 2022, which has been recognized by the United Nations. The initiative of Vision Prabaho by IIT KGP students follow this national mission of India.

“We hold a great responsibility to actively participate in dealing with the major environmental issues like the irresponsible use of plastics, waste and resource management, conservation of water body, preserving bio-diversity and reducing carbon footprint in and around the campus. Many of us emphasize human-induced environmental changes in recent years. We wanted to apply our own understanding to spread awareness and make changes on the campus. To us “Vision Prabaho” is an IDEA that should remain, even after we leave this beautiful campus,” opined the founding members, Biswarup, Pragnaditya, Sirsendu and Sudeshna, research scholars at IIT KGP.

The group will be working on increasing green cover and personal care for trees. Under the ‘You Plant, You Care’ campaign students are being encouraged to plant trees and nurture them which will carry their legacy even after they graduate. In a recently held photography competition on campus flora, the winners were awarded potted plants by Mrs. Chakrabarti who inspired them to care for the plants and conceived the campaign.

“There are about 30 students’ societies in the campus at present who are engaged in socio-cultural, sports, co-curricular, activities. “Vision Prabaho”, however, will be a unique society, not just in IIT KGP, but across all IITs, considering the fact that our campus is a mini-township and is witnessing challenges quite similar to urban areas though at a smaller scale though fortunately, we have a huge cover of greenery,” said Prof. William Mohanty, President, Technology Students’ Gymkhana at IIT KGP.