IIT Kharagpur unveiled the increasing ozone pollution in Antarctica

IIT Kharagpur researchers revealed significant increase of ozone pollution in the Antarctic troposphere for the past 25 years, which is a concern as the region is far from the industries and continental emission sources.

A recent scientific study analysed the significant increase of Surface Ozone and Tropospheric Ozone in Antarctica for the past 25 years. The research findings were supported by surface-based and ozonesonde measurements in Antarctica.

“The increasing trend in ozone pollution across Antarctica would have a profound impact on the future climate of one of the most climate-sensitive regions on the Earth, as tropospheric ozone has warming feedback to the Earth’s climate, and that can accelerate melting of sea-ice, changes in water masses, and damages to the ecosystem”, said Prof Jayanarayanan Kuttippurath, the lead researcher and Assistant Professor of Centre for Oceans, Rivers, Atmosphere, and Land sciences at IIT Kharagpur.

 The research findings are published in Environmental Science and Technology Journal of the American Chemical Society (https://doi.org/10.1021/acs.est.0c08491) on June 16, 2021. In this regards, American Chemical Society made the press release on the same date (https://www.acs.org/content/acs/en/pressroom/presspacs/2021/acs-presspac-june-16-2021/ozone-pollution-has-increased-in-antartica.html).

The increasing pollution in a remote region with no industries, no significant population, very limited anthropogenic activities and about 6500 km away from the equator, is a serious concern and suggests substantial anthropogenic pollution across the latitudes.  Dominant sources of ozone are both natural and from human-related sources. The researchers compiled the ozone data measured between 1992 and 2018 at ground level and through the atmosphere, from the lower atmosphere into the ozone layer, at eight stations across Antarctica.

“Making measurements and monitoring the environment at remote locations such as Antarctica is very important because of its remoteness and constant clean air there making it easier to detect even slight changes related to global scale, and thus can expose first signals of global change”, added Prof Virendra Kumar Tewari, the IIT Kharagpur Director.

 

“The increasing trend in ozone pollution is significant even after accounting for the natural variability, and we find substantial amounts of ozone pollution is being transported from neighbouring regions,” said Mr. Pankaj Kumar, the research scholar from the Centre of Oceans, Rivers, Atmosphere and Land Science of IIT Kharagpur as well as the another lead author of the paper.

The authors acknowledged the Department of Science and Technology (DST), Ministry of Education (MoE), and Ministry of Earth Science (MoES) for facilitating the study. They also thanked Dr M Ravichandran, the Director of National Centre for Ocean and Polar Research Goa, India for his encouragement and support for this study.

Media Contact: Prof Jayanarayanan Kuttippurath, Assistant Professor

Email: jayan@coral.iitkgp.ac.in, Ph. no.: +91-9475472847

Contact: Paramita Dey, Junior Assistant

Email: media@iitkgp.ac.in, Ph. No.: +91-3222-282004

 

Ammonia Hotspot Trends in India – First-time observations from India

Indo-Gangetic Plain an atmospheric ammonia hotspot but India’s overall trends look promising

Agro fertilizers containing high levels of ammonia have long been designated as a hazardous material for human health. For the first time in India, the seasonal and inter-annual variability of atmospheric ammonia emitted by the agricultural sector has been analyzed by researchers from IIT Kharagpur in collaboration with IITM Pune and European researchers. And the results are in agreement with the long-held apprehension of global environmentalists – the Indo-Gangetic Plain (IGP) is indeed the global hot-spot of atmospheric ammonia (NH3) due to intense agricultural activities and fertilizer production there. 

Using IASI satellite measurements to analyze the seasonal and inter-annual variability of atmospheric NH3 over India for the period 2008–2016, the researchers observed atmospheric ammonia growing rapidly at a rate of 0.08% annually during the summer-monsoon (Kharif crop period) season from June to August. The study further confirmed a direct correlation between NH3 emissions and fire counts and reports a high volume of atmospheric ammonia in the same season. They delineated the data for global industrial, agricultural, and natural NH3 hotspots.

The satellite data we collected for agricultural emissions show a positive correlation of atmospheric ammonia with total fertilizer consumption and temperature since high temperature favours volatilization and is negatively correlated with total precipitation as wet deposition helps removal of atmospheric ammonia,” explained Prof. Jayanarayanan Kuttippurath from IIT Kharagpur’s Centre for Oceans, Rivers, Atmosphere. 

Atmospheric ammonia is typically generated due to agricultural activities including the use of nitrogenous fertilizers, manure management, soil and water management practices and animal husbandry. It is very dynamic as it is constantly exchanged between the atmosphere and biosphere. In India, there has been a lack of detailed information about atmospheric ammonia, which is a significant contributor to atmospheric pollution and deterioration of air quality. This is particularly important for IGP as there are many cities including New Delhi.

This study titled “Record high levels of atmospheric ammonia over India: Spatial and temporal analyses” and published recently in Elsevier journal “Science of the Total Environment”, is pioneering research from India in measuring the dynamics of atmospheric ammonia over the region and validated the data supporting India’s commitment to reduce atmospheric pollution and development of global pollution control initiatives. Apart from IGP, data from across the country show some regional hotspots in northwest and southeast India. The study also mentions that there are positive trends in atmospheric NH3 over the agricultural areas of the United States, China and Europe, about 1.8–2.61% annually, depending on regions. However, the general trend in atmospheric ammonia over India is negative in most seasons.

“Observing the overall trend, we can therefore assert to being sincere to our pledge at the Paris Climate Summit towards reducing atmospheric emissions through initiatives under the National Clean Air Programme though we have to be relentless in our efforts to reduce the emissions at the Indo Gangetic Plain, which would otherwise have detrimental effects on the human health, ecosystems and climate,” added Prof. Kuttippurath.

Deliberating on possible remedies co-authors Mr. Ajay Singh and Prof. Nirupama Mallick from the IIT Kharagpur’s Department of Agricultural and Food Engineering emphasized the wider adoption of precision farming along with seasonal restrictions on the use of fertilizers.

“Agriculture, in its conventional form, contributes significantly to the atmospheric emission of gaseous ammonia that plays a key role in the deterioration of air quality over the whole of India by actively contributing to the formation of secondary aerosols. This demands regulations on the amount of fertilizer application in cropping seasons in arable lands, in place of conventional blanket recommendation practices, along with viable strategies to curb farm emissions” remarked Prof. Nirupama Mallick from the Dept. of AGFE.

Citation: J. Kuttippurath, A. Singh, S.P. Dash, N. Mallick, C. Clerbaux, M. Van Damme, L. Clarisse, P.-F. Coheur, S. Raj, K. Abbhishek, H. Varikoden, Record high levels of atmospheric ammonia over India: Spatial and temporal analyses, Science of The Total Environment, Volume 740, 2020, 139986, ISSN 0048-9697, https://doi.org/10.1016/j.scitotenv.2020.139986.

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Research: Dr. Jayanarayanan Kuttippurath, Assistant Professor, Centre for Oceans, Rivers, Atmosphere and Land Sciences (CORAL), IIT Kharagpur, Email: jayan@coral.iitkgp.ac.in

Media: Shreyoshi Ghosh, Executive Officer (Media & Communication), IIT Kharagpur, Email: shreyoshi@adm.iitkgp.ac.in

For news and information please visit: https://kgpchronicle.iitkgp.ac.in

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How safe is your tea in a paper cup?

IIT Kharagpur Research Gives Evidence of Microplastic Pollution in the Hot Liquid Consumed from Disposable Paper Cups

With the current crusade against single-use plastic, disposable paper cups are on the rise especially for consuming water and hot beverages. But even these cups are not without peril. Recent research by IIT Kharagpur has confirmed contamination of the hot liquid served in paper cups due to the degradation of microplastics and other hazardous components from the lining material of the cup. 

Paper cups are usually lined by a thin layer of hydrophobic film which is made of mostly plastic (polyethylene) and sometimes co-polymers to hold the liquid in the paper cup. Within 15 minutes this microplastic layer degrades as a reaction to hot water, says the first of its kind study conducted in India by Dr. Sudha Goel, Associate Professor at the Dept. of Civil Engineering and research scholars Ved Prakash Ranjan and Anuja Joseph studying Environmental Engineering and Management.

The paper ‘Microplastics and other harmful substances released from disposable paper cups into hot water’ has been published in the Journal of Hazardous Materials recently. [https://doi.org/10.1016/j.jhazmat.2020.124118]. 

“According to our study, 25,000 micron-sized (10 µm to 1000 µm) microplastic particles are released into 100 mL of hot liquid (85 – 90 oC) residing in the paper cups for 15 mins. Thus, an average person drinking 3 regular cups of tea or coffee daily, in a paper cup, would be ingesting 75,000 tiny microplastic particles which are invisible to the human eyes,” says Prof. Sudha Goel. 

The researchers followed two different procedures – in the first process, hot ultrapure (MilliQ) water (85–90 ◦C; pH~6.9) was poured into the disposable paper cups,  and it was allowed to sit for 15 mins. The homogeneously mixed water was then analyzed for the presence of microplastics as well as additional ions that may have leached into the liquid from the paper cups. In the second process, paper cups were initially dipped in lukewarm (30–40 °C) MilliQ water (pH~6.9). Thereafter the hydrophobic film was carefully separated from the paper layer and exposed to hot MilliQ water (85–90 °C; pH~6.9) for 15 mins. and Changes in the physical, chemical, and mechanical properties of the plastic films were examined before and after exposure to hot water.

Explaining the exposure of 15 minutes, Prof. Goel linked its basis to a survey wherein the respondents confirmed consuming their beverage within 15 mins of obtaining it.

“Besides the result of the survey, it was also observed that within this time, the beverage attained the ambient temperature,” she said. 

The samples of paper cups were collected from popular stores across Kharagpur, West Bengal. “Our study indicates most plastic layers lining the paper cups were of HDPE (High-density polyethylene) grade, whereas only very few paper cups were lined with a copolymer of cellulose. However, the release of microplastics into the hot water was consistent in all samples irrespective of their grades,” remarked researcher Ved Prakash Ranjan.  

Apart from the presence of ions, the study also revealed that the plastic layer was laden with toxic heavy metals like Palladium, Chromium, and Cadmium.

“Our hypothesis on the degradation of the plastic layer after exposure to hot water was confirmed through images obtained from the atomic force and scanning electron microscopy. Also, another study on the mechanical properties of the plastic film proved its deformation upon exposure to heat,” explained researcher Anuja Joseph.

What could be the effect of long-term exposure to such microplastics? 

Prof. Sudha Goel expressed concern over the bioaccumulation of microplastics in human and animal bodies.

“These microplastics can further act as carriers for contaminants like ions, toxic heavy metals and organic compounds which are similarly hydrophobic in nature thus allowing them to conveniently cross over to the animal kingdom. When ingested, the health implications could be serious,” she opined.

While the research to study the health impact of microplastics is relatively limited, researchers are assertive about adverse effects from both the environmental and health point of view. Such materials have been repeatedly linked with child growth and organ development, reproduction issues, disruption of hormones, obesity etc. At a spring conference at the Rutgers Center for Urban Environmental Sustainability, a research group presented the possibility of passing microplastics from the mother’s body to even the fetus.

“These contaminants can bioaccumulate in organisms leading to health issues like the disruption of the endocrine system, reproductive defects, cancer, neurological disorders and other effects. There could be further health challenges such as the impact on the sense organs, immune dysfunction or even cancer. That remains for domain experts to confirm while we can foresee the environmental mayhem these particles are going to cause if gone unchecked,” stated Prof. Goel.

Several states in India have been mulling over restricting the use of paper cups but feasible alternatives are not yet on deck. Referring to the situation, Director, Prof. Virendra K Tewari called for careful consideration before the promotion of replacements for bio-hazardous products and environmental pollutants. He said,

“We have been quick to replace plastics cups and glasses with disposable paper cups. While the need was crucial we have to find eco-friendly products. India has traditionally been a country promoting sustainable lifestyle and may be it is time that we look into our roots for corrective measures.”

He wondered if earthen products can meet the consumer demand for disposable plastic and paper cups.

“Atmanirbhar Bharat has to be in our thinking before we adopt it in our lifestyle and the country’s economy and everything we do should have a reflection of that thought process and thereby in our consumption behaviour,” he added.


Cite this paper: Ranjan VP, Joseph A and S Goel [2020] Microplastics and other harmful substances released from disposable paper cups into hot liquids, Jour. of Hazardous Materials, 404 (124118): 1-12. https://doi.org/10.1016/j.jhazmat.2020.124118


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Contacts:

For Research: Dr. Sudha Goel, Associate Professor (Environmental Engineering & Management), Civil Engineering Department, sudhagoel@civil.iitkgp.ac.in

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AI to Detect How Safe is Your Drinking Water

Researchers from IIT Kharagpur have developed an AI-based prediction model for  detecting Arsenic pollution in drinking water

Arsenic has been a menace in Eastern India especially along the banks of the Ganga for almost two decades now, putting millions of people at severe health risk. Researchers have been studying the distribution patterns of the contaminated groundwater for years to develop a large-scale ecological and environmental framework addressing this challenge in the region. For the first time, a breakthrough has been achieved. A group of researchers from IIT Kharagpur has successfully predicted the distribution of groundwater arsenic and human health risk in the affected areas using AI algorithms on environmental and geological and human usage parameters.

The researchers have delineated the high and low arsenic zones across the entire delta using artificial intelligence and quantify the number of people exposed. This study has led to the development of probabilistic models of arsenic occurrence, exposure and human health risk assessment within the delta region. The model shows a strong association of ‘surficial aquitard thickness’ and ‘groundwater-fed irrigation’ to regional-scale As-hazard.

Among the worst affected zones are the districts of Nadia (93%) and Murshidabad (82%). The study has been recently published in the international journal Science of The Total Environment. [Download Paper]

“Our AI models predict the occurrence of high arsenic in groundwater across more than half of the Ganges River delta, covering more than 25% area extent in each of the 19 out of 25 administrative zones in West Bengal. A total of 30.3 million people are estimated to be exposed to severely high As-hazard within the Ganges river delta,” said lead author Madhumita Chakraborty at IIT Kharagpur’s Dept. of Geology and Geophysics.

While the predictive model framework would prove to be vital typically for the identification of drinking water sources in arsenic affected areas of West Bengal, it can be used in other parts of the country, which are also suffering from severe groundwater pollutants, said the researchers.

“Eventually, all this information forms the baseline knowledge for the recently initiated Jal Jeevan Mission of the Government of India. The mission is based on providing safe drinking water to every household of the country within 2024 and the outcome of this provides the information for the location of safe groundwater, which is the primary source of drinking water for most of India,” opined Prof. Abhijit Mukherjee from the Dept. of Geology and Geophysics who is leading the research.

It is to be noted that Eastern India and Bangladesh, which source more than 80% of its drinking water from groundwater sources, are coping with this issue of naturally-sourced arsenic mass poisoning. The studies conducted until now were unable to offer an effective model for policy decisions due to the delineation of the local extent and geochemical mechanisms for arsenic pollution.

The researchers from IIT Kharagpur thus opted for AI which is now being used across the world to successfully model the distribution of groundwater contaminants.

“Such successful use of artificial intelligence in geoscience enables us to find answers and build prima-facie understanding before further detailed field-based investigation or validation. However, such regional-scale models do not completely eliminate the need for field investigation in many cases; especially for groundwater contaminants like arsenic which is known to exhibit well-to-well variability in concentration,” added Prof. Mukherjee.

Citation: Chakraborty et al. (2020). Modeling regional-scale groundwater arsenic hazard in the transboundary Ganges River Delta, India and Bangladesh: Infusing physically-based model with machine learning. Science of The Total Environment. Volume 748, 15 December 2020, 141107 [https://doi.org/10.1016/j.scitotenv.2020.141107]

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Research Information: Prof. Abhijit Mukherjee, abhijit@gg.iitkgp.ac.in

Institute Information: Prof. B N Singh, Registrar, registrar@hijli.iitkgp.ac.in

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It’s Illumination Time

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Walking down the halls of residence at the IIT Kharagpur campus during the Diwali festival one would come across giant bamboo structures and busy students tying earthen lamps (diyaas) to them in patterns. There is no rush for firecrackers among the 12000 strong student population of IIT Kharagpur but a wait for the Diwali eve when any visitor would be awed by the lighted canvas telling stories from Indian history and mythology, Indian or global political issues, socio-economic issues etc.

When the country is debating the ban on firecrackers and whether to extend the same to other festivities and celebrations; when people are still hoping to get lucky with the green crackers which have been out of stock in the market; when the world is still debating about climate change with groups trying to find perspectives in the voices raised by climate change evangelists; the students in their late teens and 20s have quietly established a tradition of going green every Diwali for the past four decades.

 “Our campus is stretched across 2100 acres but the halls of residence are located in a particular area. Think what would we do to our homes at Kgp if thousands of firecrackers are burnt for an entire evening! Instead, in typical IIT KGP style our seniors in the early 1980s turned this challenge into an opportunity and pledged to shun air pollution and replace it with creativity, teamwork, innovation and leading to creating art forms which was named Illumination,” said a proud Akshat Jain, 3rd year UG student of Agricultural and Food Engineering department, who also heads the Public Relations Chair of Technology Students Gymkhana, the student nerve centre of IIT Kharagpur.

In the true spirit of Diwali, Illumination disseminates a wave of excitement and enthusiasm throughout the campus. It marks the triumph of endless night-outs, mammoth hours of planning and exemplary teamwork uniting the whole campus community and making a yearly statement of how nature can be saved following a long-standing tradition. To begin with, the basic raw materials comprising of steel wires, bamboo, and diyas, students transform them into magnificent structures with unique themes varying with Halls of residence which shine against the dark making every KGPian proud and spirited. The diyas are hung to designing of gigantic canvasses made of bamboo structures or Chatais about 20 ft high with an average area of 1500 sq.ft. On the eve of Diwali as the visitors start coming in one hall after another start lighting up these diyas creating a mesmerising view to which only professional artistes may be able to compete.

“This culture is followed by 23 halls of residence where artist’s canvases are created and these artistes are none other than students of IIT Kharagpur. Such a non-polluting way of celebration benefiting the local community both environmentally and economically in this scale would be difficult to find elsewhere in the world to the best of my knowledge. Illumination I would say, is the indigenous festival of IIT Kharagpur,” beamed Akshat.

Talking about this green Diwali tradition, Officiating Director of IIT Kharagpur Prof. Sriman Kumar Bhattacharyya said, “Illumination is done with a grandeur without causing any harm to the environment. It is a green process because the students do not burn any material which could be considered as highly pollutant. This could also be observed the day following Diwali when the air at the IIT Kharagpur campus as fresh as the other days unlike the scenario in most urban areas.”

This led to a direct, positive impact on the campus environment by preventing unwanted noise and air pollution while at the same time saving large on electricity expenditure on the day of Diwali by going traditional. And then there is the novelty of supporting the livelihood of local shopkeepers selling the materials required for this celebration. 

Together with Illumination is another indispensable part of Diwali at IIT Kharagpur – “Rangoli”. The IIT KGP Rangoli is very different from what is traditionally thought of as Rangoli per se. These are huge murals made on the floor with colors mixed with sand. The sand is sifted at least a hundred times to get a fineness that is silvery smooth when running through the fingers. The colours are sourced locally or sometimes, from South India, for some colours that are rare. Students work on deciding the theme and design and ultimately executing the work. The themes are multifarious – scenes from myths, folklore or contemporary accounts of violence or victory, addressing social issues and achievements of Indians.

This unique festival of IIT Kharagpur has more takers than the campus residents and students. Just like pandal hopping, thousands of visitors from outside the campus do hostel hopping on the eve of Diwali before the diyas run out of oil and the wind takes charge. The festival is also highly popular with the international students who enthusiastically take part in the preparation in their respective halls of residence.

Prof. Anandroop Bhattacharya, Associate Dean of International relations of the institute who was alumnus of 1997 batch said that “illumination  event is something every KGPian is proud of. Nowhere is  Diwali celebrated in the world as it is done at  IIT KGP. Through decades we have been able to show that there is a clean and green way of celebrating Diwali.”

To share the art form with more connoisseurs from the global community, this year the Office of International Relations launched a holistic short-term certification program Dyuti focussing on Indian science, technology, heritage and culture with a workshop on Illumination and Rangoli. International students of various nationalities who are already studying in India joined the week-long programme are to join the day-long workshop at the halls of residence where they will take part in the making of the grand designs and take back home an experience which can transform festivities across the globe to cleaner celebrations without missing the joy of it.